Spider Not Spider Killer
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Product identifier |
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Chemical Name |
Mixture |
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CAS No. |
Mixture |
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Trade Name |
Spider Not |
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Product code |
10-500987 |
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EPA Identification Number(s) |
EPA Reg. No. 358-111 |
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Relevant identified uses of the substance or mixture and uses advised against |
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Identified Use(s) |
Pesticidal spray |
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Uses Advised Against |
It is a violation of Federal law to use this product in a manner inconsistent with its labeling. |
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Company Identification |
Spray Products Corporation P.O. Box 737 Norristown, PA 19404 |
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Telephone |
(610) 277-1010 |
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Fax |
(610) 277-4390 |
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E-Mail (competent person) |
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Emergency telephone number |
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Emergency Phone No. |
Transportation Emergency: CHEMTREC 24 hr. 1-800-424-9300 / 1 (703) 527-3887 (Collect calls accepted) |
Classification of the substance or mixture |
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OSHA HCS (29 CFR 1910.1200) |
Flam. Aerosol 1; Compressed dissolved gas; Asp. Tox. 1; STOT SE 3; Skin Irrit. 2 |
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Label elements |
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This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non pesticide chemicals. The hazard information required on the pesticide label is reproduced in section 15 of this SDS. |
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Hazard Symbol |
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Signal word(s) |
DANGER |
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Hazard Statement(s) |
Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May cause drowsiness or dizziness. |
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Precautionary Statement(s) |
Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wash hands and exposed skin after use. Wear protective gloves/protective clothing/eye protection/face protection. Protect from sunlight and do not expose to temperatures exceeding 50 ºC/122 ºF. |
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Other hazards |
Contains: Contains: Contains: N-Octyl Bicycoheptane Dicarboximide (CAS No. 52315-07-8, 0.00375%); Esfenvalerate (CAS No. 66230-04-4, 0.00375%); Prallethrin (CAS No. 23031-36-9, 0.00045%); - May produce an allergic reaction in persons already sensitized. Harmful to aquatic life with long lasting effects. |
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Additional Information - ** May produce an allergic reaction in persons already sensitized. * The exact percentage withheld as a trade secret in accordance with 29 CFR 1910.1200. |
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Description of first aid measures |
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Inhalation |
Move person to fresh air. If breathing is laboured, administer oxygen. If symptoms develop, obtain medical attention. |
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Skin Contact |
Wash affected skin with soap and water. If symptoms develop, obtain medical attention. Take off contaminated clothing and wash it before reuse. |
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Eye Contact |
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. |
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Ingestion |
Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting. Do not give anything by mouth to an unconscious person. |
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Most important symptoms and effects, both acute and delayed |
Aspiration of droplets may cause pulmonary oedema. May produce an allergic reaction in persons already sensitized. |
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Indication of any immediate medical attention and special treatment needed |
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
Extinguishing media |
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-Suitable Extinguishing Media |
Extinguish with carbon dioxide, dry chemical, foam or waterspray. |
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-Unsuitable extinguishing Media |
Do not use water jet. |
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Special hazards arising from the substance or mixture |
None anticipated. |
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Advice for fire-fighters |
A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep containers cool by spraying with water if exposed to fire. |
Personal precautions, protective equipment and emergency procedures |
Eliminate sources of ignition. Avoid contact with skin and eyes. Avoid breathing spray. Wear protective gloves/eye protection. |
Environmental precautions |
Prevent liquid entering sewers, basements and workpits. |
Methods and material for containment and cleaning up |
Cover spills with inert absorbent material. Transfer to a container for disposal or recovery. |
Reference to other sections |
None |
Additional Information |
None |
Precautions for safe handling |
Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Avoid contact with skin and eyes. Avoid breathing spray. Wash hands thoroughly after handling. Use product in a well-ventilated area only. |
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Conditions for safe storage, including any incompatibilities |
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-Storage temperature |
Keep in a cool, well ventilated place. Protect from sunlight. °F. |
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-Incompatible materials |
This product should be stored away from sources of strong heat or oxidising chemicals. Strong Acids and Alkalis. |
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Specific end use(s) |
Pesticidal spray |
Occupational Exposure Limits |
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#Assure minimum oxygen content of work atmosphere. |
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Recommended monitoring method |
NIOSH 6603 (Carbon dioxide); NIOSH 5026 (Oil mist; mineral) |
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Exposure controls |
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Appropriate engineering controls |
Provide adequate ventilation to ensure that the occupational exposure limit is not exceeded. |
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Personal protection equipment |
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Eye/face protection |
Not normally required. Do not get in eyes. |
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Skin protection (Hand protection/ Other) |
Wear suitable gloves if prolonged skin contact is likely. Check with protective equipment manufacturer's data. |
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Respiratory protection |
Normally no personal respiratory protection is necessary. In case of insufficient ventilation, wear suitable respiratory equipment. Check with protective equipment manufacturer's data. |
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Thermal hazards |
Not normally required. Use gloves with insulation for thermal protection, when needed. |
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Environmental Exposure Controls |
Avoid release to the environment. |
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Information on basic physical and chemical properties |
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Appearance |
Aerosol spray |
Color. |
Clear rless |
Odor |
Petroleum spirit |
Odor Threshold (ppm) |
Not available |
pH (Value) |
Not available |
Not available |
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Boiling point/boiling range (°C): |
> 200 (> 392 °F) |
Flash Point (°C) |
60 - 93 (140 - 199 °F) |
Evaporation Rate |
Not available |
Flammability (solid, gas) |
Extremely flammable aerosol. |
Explosive Limit Ranges |
Not applicable |
Vapor pressure (Pascal) |
Not available |
Vapor Density (Air=1) |
Not available |
Density (g/ml) |
Not available |
Solubility (Water) |
Not available |
Solubility (Other) |
Not available |
Partition Coefficient (n-Octanol/water) |
Not available |
Auto Ignition Point (°C) |
Not available |
Decomposition Temperature (°C) |
Not available |
Kinematic Viscosity (cSt) |
< 20.5 @ 40 °C |
Explosive properties |
Not available |
Oxidizing properties |
Not available |
Other information |
Not available |
Reactivity |
Stable under normal conditions. |
Chemical stability |
Stable. |
Possibility of hazardous reactions |
None anticipated. |
Conditions to avoid |
Avoid contact with heat and ignition sources. |
Incompatible materials |
Strong oxidising agents. Strong Acids and Alkalis. |
Hazardous decomposition product(s) |
Carbon monoxide, Carbon dioxide, Acrid smoke |
Exposure routes: Inhalation, Skin Contact, Eye Contact
Substances in preparations / mixtures |
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Distillates (petroleum), hydrotreated light (CAS No. 64742-47-8) - By analogy with similar materials: |
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Acute toxicity (calculated / estimated) |
Oral: LD50 >5000 mg/kg-bw Dermal: LD50 >2000 mg/kg-bw Inhalation: LC0 ≥5.28 mg/l (Vapour), 4-hr. rat - May cause drowsiness or dizziness. |
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Irritation/Corrosivity |
Causes skin irritation. Repeated exposure may cause skin dryness or cracking. |
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Sensitisation |
It is not a skin sensitiser. |
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Repeated dose toxicity |
Oral: NOEAL 750 mg/kg Dermal: NOEAL 0.5 ml/kg bw Inhalation: NOAEL ≥1000 mg/m3 |
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Carcinogenicity |
It is unlikely to present a carcinogenic hazard to man. |
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Mutagenicity |
Not to be expected |
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Reproductive toxicity |
Not to be expected |
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Other information |
Contains: Contains: Contains: N-Octyl Bicycoheptane Dicarboximide (CAS No. 52315-07-8, 0.00375%); Esfenvalerate (CAS No. 66230-04-4, 0.00375%); Prallethrin (CAS No. 23031-36-9, 0.00045%); May produce an allergic reaction in persons already sensitized. |
Ecotoxicity |
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Distillates (petroleum), hydrotreated light (CAS No. 64742-47-8) - By analogy with similar materials: |
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Short term |
LC50 (96 hour): 2.5 mg/L (fish) EC50 (48 hour): 1.4 mg/L (crustacea) EC50 (72 hour): 1.3 mg/L (algae) |
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Long Term |
NOEC (28 days): 0.098 mg/L (fish) LOEC (21 days): 1.2 mg/L (crustacea) LOEL (72 hour): 1 mg/L (algae) |
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Persistence and degradability |
Not available. |
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Bioaccumulative potential |
Not available. |
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Mobility in soil |
Not available. |
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Results of PBT and VPVB assessment |
Not classified as PBT or vPvB. |
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Other adverse effects |
None known. |
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Other information |
Contains: Contains: N-Octyl Bicycoheptane Dicarboximide (CAS No. 52315-07-8, 0.00375%); Esfenvalerate (CAS No. 66230-04-4, 0.00375%); Prallethrin (CAS No. 23031-36-9, 0.00045%); Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. |
Waste treatment methods |
Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice. |
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U.S. DOT |
Sea transport (IMDG) |
Air transport (ICAO/IATA) |
UN number |
1950 |
1950 |
1950 |
Proper Shipping Name |
Aerosols, flammable |
Aerosols, flammable |
Aerosols, flammable |
Transport hazard class(es) |
2.1 |
2.1 |
2.1 |
Packing group |
Not applicable |
Not applicable |
Not applicable |
Environmental hazards |
None assigned |
None assigned |
None assigned |
Special precautions for user |
None assigned |
None assigned |
None assigned |
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable |
Safety, health and environmental regulations/legislation specific for the substance or mixture: |
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TSCA (Toxic Substance Control Act) - Inventory Status: All components listed or polymer exempt. |
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EPA FIFRA Information for SDS Section 15 (Regulatory Information):
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non pesticide chemicals.
The hazard information required on the pesticide label is reproduced below:
CAUTION: Harmful if swallowed. Avoid prolonged breathing of spray mist or repeated contact with skin. Do not apply to humans, pets or birds. Wash hands Wash thoroughly with soap and water after using. Do not spray near fish or aquariums. Do not use in dairy barns or poultry houses. Avoid contamination of feed, foodstuffs or water sources. Do not spray painted walls, upholstery, lamps, rugs, finished wood or other decorative surfaces. Extremely flammable. Contents under pressure. Keep away from fire, sparks and heated surfaces. Do not puncture or incinerate container. Expousre to temperatures above 130 °F may cause bursting. DISPOSAL: Do not reuse container. Wrap container and put in trash collection. -------- |
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Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4): |
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Chemical Name |
CAS No. |
Typical %wt. |
RQ (Pounds) |
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None |
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SARA 311/312 - Hazard Categories: |
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SARA 313 - Toxic Chemicals (40 CFR 372): |
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Chemical Name |
CAS No. |
Typical %wt. |
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None |
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SARA 302 - Extremely Hazardous Substances(40 CFR 355): |
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Chemical Name |
CAS No. |
Typical %wt. |
TPQ (pounds) |
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None |
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California Proposition 65 List: |
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Chemical Name |
CAS No. |
Type of Toxicity |
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None |
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The following sections contain revisions or new statements: 1-16. Date of preparation: January 5, 2017 |
Hazard Statement(s) and Risk Phrases Listed in: SECTION 2:/ SECTION 3: Hazard Statement(s) - H227: Combustible liquid. - H302: Harmful if swallowed. - H304: May be fatal if swallowed and enters airways. - H315: Causes skin irritation. - H317: May cause an allergic skin reaction. - H331: Toxic if inhaled. - H336: May cause drowsiness or dizziness. - H400: Very toxic to aquatic life. - H410: Very toxic to aquatic life with long lasting effects. - H412: Harmful to aquatic life with long lasting effects.
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Training advice: None. |
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.
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